Implanting Cobalt Atom Clusters within Nitrogen-Doped Carbon Network as Highly Stable Cathode for Lithium-Sulfur Batteries.

Abstract

Realization of highly efficient sulfur electrochemistry, as well as the high capacity of lithium-sulfur (Li-S) batteries, can be achieved by the scientific construction of electrode host materials. In this study, using molten NaCl, a 3D porous nitrogen-doped carbon with uniformly embedded Co atom clusters (Co/PNC) is developed by pyrolyzing the precursors with NaCl at high temperatures. In the composite structure, a network carbon skeleton containing hierarchical pores acts as an advanced matrix for sulfur electrodes, and the doping of N and Co is subject to inhibit the shuttle of long-chain lithium polysulfides through chemical adsorption. The Co/PNC, with the optimized amount of Co, delivers an initial specific capacity of 1105.4 mAh g-1 at 0.2 C with a capacity drop of only 0.064% after the cell is charged and discharged for 300 cycles at 1 C, revealing its potential in promoting the large-scale application of Li-S batteries.