Abstract
Abstract. Recent studies have shown that surface ozone (O3) concentrations over central eastern China (CEC) have increased significantly during the past decade. We quantified the effects of changes in meteorological conditions and O3 precursor emissions on surface O3 levels over CEC between July 2003 and July 2015 using the GEOS-Chem model. The simulated monthly mean maximum daily 8 h average O3 concentration (MDA8 O3) in July increased by approximately 13.6 %, from 65.5±7.9 ppbv (2003) to 74.4±8.7 ppbv (2015), comparable to the observed results. The change in meteorology led to an increase in MDA8 O3 of 5.8±3.9 ppbv over the central part of CEC, in contrast to a decrease of about -0.8±3.5 ppbv over the eastern part of the region. In comparison, the MDA8 O3 over the central and eastern parts of CEC increased by 3.5±1.4 and 5.6±1.8 ppbv due to the increased emissions. The increase in averaged O3 in the CEC region resulting from the emission increase (4.0±1.9 ppbv) was higher than that caused by meteorological changes (3.1±4.9 ppbv) relative to the 2003 standard simulation, while the regions with larger O3 increases showed a higher sensitivity to meteorological conditions than to emission changes. Sensitivity tests indicate that increased levels of anthropogenic non-methane volatile organic compounds (NMVOCs) dominate the O3 increase over the eastern part of CEC, and anthropogenic nitrogen oxides (NOx) mainly increase MDA8 O3 over the central and western parts and decrease O3 in a few urban areas in the eastern part. Budget analysis showed that net photochemical production and meteorological conditions (transport in particular) are two important factors that influence O3 levels over the CEC. The results of this study suggest a need to further assess the effectiveness of control strategies for O3 pollution in the context of regional meteorology and anthropogenic emission changes.
Highlights
Tropospheric ozone (O3) is a major atmospheric oxidant and the primary source of hydroxyl radicals (OH), which control the atmospheric oxidizing capacity (Seinfeld and Pandis, 2016)
We investigate the effect of anthropogenic emissions (NOx and non-methane volatile organic compounds (NMVOCs)) on surface O3 concentrations based on the 2015 simulations
Considering that the nighttime O3 is titrated by NO and the maximum daily 8 h average O3 concentration (MDA8 O3) is a good indicator for the overall O3 pollution condition, we focus on the MDA8 O3 changes over central eastern China (CEC) between July 2003 and July 2015 instead of daily mean O3
Summary
Tropospheric ozone (O3) is a major atmospheric oxidant and the primary source of hydroxyl radicals (OH), which control the atmospheric oxidizing capacity (Seinfeld and Pandis, 2016). Previous studies have revealed the important effects of changing emission levels and varying climate conditions on tropospheric O3 in different regions. Given the scarcity of previous research, it is necessary to further quantify the contributions of emissions and meteorological conditions to surface O3 levels to deepen our understanding of the factors influencing O3 changes in China. This is a follow-up study of Sun et al (2016), who found a significant increase in summertime O3 at a regional site in north China from 2003 and 2015.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.