Abstract

Summer ozone (O3) pollution in China has become increasingly serious in recent years. This study is based on hourly data of near-surface ozone (O3) and nitrogen oxides (NOx) and volatile organic compounds (VOCs) from June to August 2020 in Yuncheng, combined with meteorological data to analyse the characteristics of O3 pollution in summer and the influence of meteorological factors, precursors, and long-range transport on O3 pollution. In this paper, the VOCs/NOx characteristic ratio method was used to explore the sensitivity of O3 generation. Backward trajectories, cluster analysis, potential source contribution factor (PSCF) analysis and concentration weight trajectory (CWT) analysis were also calculated using Trajstat software. In 2020, Yuncheng had persistent O3 pollution, with the highest concentrations in June, significantly higher than July and August. Conditions of high temperature, low relative humidity and low wind speed contribute to the O3 accumulation. VOCs are the main precursors to the local production of O3. Besides, the long-range transport analysis shows that southeast-oriented air masses are the main direction influencing summer O3 pollution. The primary potential source areas of O3 are in the central and southern part of Henan province, the north-western Anhui province, and the northern Shaanxi. In addition, northern Hubei and southwestern Shandong also influence O3 pollution in summer Yuncheng.

Highlights

  • After implementing the Chinese government’s air pollution prevention and control plan, China has achieved remarkable achievement for the frequent PM2.5 pollution in heating seasons [1,2]

  • Near-surface O3 is a typical secondary pollutant, and its primary source is the photochemical reaction of atmospheric volatile organic compounds (VOCs) and nitrogen oxides (NOx) under solar radiation conditions [7]

  • O3 concentration, (3) analysed the relationship between precursors and O3 production by using the characteristic ratio method (VOCs/NOx), (4) using potential source contribution factor (PSCF) analysis and concentration weight trajectory (CWT) analysis provided by Trajstat software to study the regional transport characteristics of O3 and its potential source areas in different seasons in Yuncheng City

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Summary

Introduction

After implementing the Chinese government’s air pollution prevention and control plan, China has achieved remarkable achievement for the frequent PM2.5 pollution in heating seasons [1,2]. Near-surface O3 concentrations are a critical factor influencing summer air quality in China. Near-surface O3 is a typical secondary pollutant, and its primary source is the photochemical reaction of atmospheric volatile organic compounds (VOCs) and nitrogen oxides (NOx) under solar radiation conditions [7]. Many related studies have discussed the causes of O3 contamination and found that the high concentration events are a combination of adverse meteorological conditions, precursor emissions and long-range transportation [10,11,12]. O3 concentration, (3) analysed the relationship between precursors and O3 production by using the characteristic ratio method (VOCs/NOx), (4) using potential source contribution factor (PSCF) analysis and concentration weight trajectory (CWT) analysis provided by Trajstat software to study the regional transport characteristics of O3 and its potential source areas in different seasons in Yuncheng City. Atmosphere 2021, 12, 1661 basis for O3 pollution control and emission reduction policy formulation in Yuncheng City and other urban clusters in the Fenwei Plain

Overview of the Study Area
Data Sources
Hysplit Model
Ozone Pollution Occurred in Summer 2020
Opposite Changes in Ozone and Its Precursors
The Influence of Meteorological Factors on Ozone Pollution
VOCs Are Critical Precursors for Ozone Formation
Transmission Trajectory Characteristics
Long-Range Transport Sources of Ozone Pollution
Conclusions
Full Text
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