Impactive cadmium modifications to enhance the structural-optical relationship in nickel borate glasses

Abstract

Cadmium-doped borate glass composition was prepared via the melt-quenching technique. The nature of the glass structure was detected by X-ray diffraction (XRD). The physical parameters, such as density (ρ) from Archimedes’ principle, molar volume (Vm), Cd2+ ions concentration (NCd), and inter-atomic distance (Ri) were evaluated, providing structural information on glass samples. Fourier transform infrared (FT-IR) analysis was used to study the fundamental vibrational modes of structural units, confirming the conversion of BO3 to BO4 units, indicating a strongly bonded and high connectivity of the network. Some important optical findings were extracted from the analysis of optical absorption spectra. For example, the mitigation in the optical band gap, the increase in Urbach energy, the deterioration in the metallization criterion, and the enhancement in the electron-phonon interaction were obtained with cadmium oxide addition. The nonlinearity characteristics were enhanced, making these glass samples have viability in the non-linear optics sector. The obtained data from the electron spin resonance (ESR) revealed that the nickel ions exist in a divalent oxidation state with octahedral symmetry. Interestingly, the optical absorption transitions of Ni2+ ions were accurately deconvoluted and assigned to octahedral and tetrahedral positions. The equations of ligand field parameters of octahedral Ni2+ ions were correctly presented. The equation of Racah C parameter was deduced for the first time. Then, the ligand field parameters, such as the ligand field strength (10 Dq), Racah parameters (B and C), and other related parameters, were precisely assessed. The covalent nature between Ni2+ ions and the ligands was detected from the nephelauxetic effect.