Impact toughening behaviour of quaternary PP/HDPE/EPDM/EP blends

Abstract

Abstract Quaternary blends of polypropylene (PP), high-density polyethylene (HDPE), ethylene–propylene diene terpolymer (EPDM) and ethylene–propylene block copolymer (EP) were prepared in a twin-screw extruder followed by injection moulding. Izod impact tests were used to determine the impact behaviour of the blends. The results showed that the quaternary blends with EPDM content ≥30 wt% exhibit superior impact strengths at 25 and −30°C. This was due to shear yielding of the matrix in the stress whitening zone of the blends containing 30 wt% EPDM. However, Izod impact tests showed that the impact energies of the blends with 25 wt% EPDM content are dependent on the HDPE concentration at 25°C. With a higher concentration of HDPE (≥15 wt%), the impact strengths at 25°C were comparable to those of the blends containing EPDM content ≥30 wt%. The blends with EPDM ≤25 wt% exhibited low-impact toughness at −30°C as featureless fracture surface and cavitation around the rubber particles were observed in the induction zone ahead of the notch tip. The measured impact strengths generally correlated well with the SEM surface morphologies.