Impact of the geometric structure parameter on the performance of dielectric barrier reactor for toluene removal.

Abstract

The reasonable geometry design of non-thermal plasma (NTP) reactor is significant for its performance. However, optimizing the reactor structure has received insufficient attention in the studies on removing volatile organic compounds by NTP. Several dielectric barrier discharge (DBD) reactors with various barrier thicknesses and discharge gaps were designed, and their discharge characteristics and toluene degradation performance were explored comprehensively. The number and intensity of current pulses, discharge power, emission spectrum intensity and gas temperature of the DBD reactors increased as barrier thickness decreased. The toluene removal efficiency and mineralization rate increased from 23.2-87.1% and 5.3-27.9% to 81.7-100% and 15.9-51.3%, respectively, when the barrier thickness reduced from 3 to 1 mm. With the increase of discharge gap, the breakdown voltage, discharge power, gas temperature and residence time increased, while the discharge intensity decreased. The reactor with the smallest discharge gap (3.5 mm) exhibited the highest toluene removal efficiency (78.4-100%), mineralization rate (15.6-40.9%) and energy yield (8.4-18.7 g/kWh). Finally, the toluene degradation pathways were proposed based on the detected organic intermediates. The findings can provide critical guidance for designing and optimizing of DBD reactor structures.