Abstract

Interpretation of reflection seismic profiles, sequential restoration, and physical modelling are presented to understand the kinematics of salt flow and diapirism in the Eastern Persian Gulf, offshore Southern Iran. Salt tectonics in this area result from the overlapping Ediacaran–Early Cambrian Hormuz Salt, which is regionally present, and Oligocene–Early Miocene Fars Salt, which is locally developed. The Hormuz and Fars salts began flowing at Cambrian(?) and Early Miocene times, respectively. Diapirs fed by the Hormuz Salt rose passively during Palaeozoic and Mesozoic times and were rejuvenated by contractional deformation events in the Cenozoic. Fars-Salt structures exist either as salt walls and anticlines around those diapirs of Hormuz Salt that developed allochthonous salt bodies during a Palaeocene–Eocene contractional squeezing before deposition of the Fars Salt, or as gentle shallow salt pillows above deep pillows of Hormuz Salt, suggesting a kinematic linkage. Flow of Fars Salt was mainly triggered by differential sedimentary loading. It seems that its lateral flow kinematics was controlled by the behaviour of the underlying Hormuz-Salt sheets. More than ~10-km-long salt sheets were efficiently evacuated back towards the Hormuz-Salt diapir, and consequently, maintained the Fars-Salt evacuation and flow to the same direction, accompanied by welding of both salt layers. Conversely, smaller, less than ~3-km-long salt sheets allowed limited salt evacuation or rearrangement that was probably still sufficient to trigger Fars-Salt flow near the central (Hormuz-Salt) diapir. Fars-Salt evacuation was enhanced by differential sedimentary loading, resulting in incipient primary welds. Subsequently, the depocentres migrated towards the areas of available Fars Salt away from the central diapir. In both cases, layer-parallel shortening related to regional contraction probably played also a role in triggering the Fars-Salt flow at Early Miocene, but was more influential at later stages by squeezing the salt structures (Hormuz and Fars) since about Late Miocene onwards.

Highlights

  • Three organic fertilizers (EDTA (Ethylenedinitrilotetraacetic acid), EDDS (Ethylenediamine-N, N′-disuccinic acid) and DTPA (Diethylene triamine pentaacetic acid)) were tested as Fe-complexes in photo-Fenton process at natural pH for micropollutants (MPs) abatement and simultaneous E.coli inactivation

  • A low stability of iron chelates causes a fast abatement of MPs but, at the same time, quick iron precipitation causing a decrease in the process efficiency

  • The capability of three Fe-complexes (EDDS, EDTA and DTPA) as iron sources has been demonstrated in photo-Fenton process for micropollutants abatement in Membrane Bioreactor and Conventional Activated Sludge effluents

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Summary

Introduction

Three organic fertilizers (EDTA (Ethylenedinitrilotetraacetic acid), EDDS (Ethylenediamine-N, N′-disuccinic acid) and DTPA (Diethylene triamine pentaacetic acid)) were tested as Fe-complexes in photo-Fenton process at natural pH for micropollutants (MPs) abatement and simultaneous E.coli inactivation. Other chelating agents, like DTPA, which presents high stability with iron, shows low kinetic rates in MPs abatement In such case, continuous MPs degradation was observed, achieving good removals at the end of the treatment. The behavior of EDDS, EDTA and DTPA was studied in different wastewater effluents (López-Vinent et al, 2020b) and was discussed regarding the evolution of iron during the experiment These results displayed the necessity to search for chelating agents whose use could avoid high iron precipitation and lead to fast kinetic rates in MPs degradation. For this reason, mixtures of EDDS, EDTA and DTPA were used in this study. The turbidity, DOC and alkalinity can affect the photo-chemical reactions due to light scattering, competition for hydroxyl radicals due to the organic matter present in the matrix and hydroxyl radicals scavenging due to the presence of carbonate and bicarbonate

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