Abstract

Relative humidity (RH) changes are a natural environmental effect that forces organic materials to a constant cycle of achieving equilibrium. The present work is part of an ongoing research based on the hypothesis that the inevitable deleterious effects of the RH natural cycle may be prevented or minimized if a deformation threshold is assigned to each monitored endangered object prior to exposure to structural damage. In this paper the characterization of the behavior of a softwood sample (1.0 cm thick) submitted to RH abrupt cycles has been performed, in terms of mass and rate of displacement of the surface. The exemplary study is based on the concept of recording the RH impact directly from the material surface, allowing us to identify diversity in reaction with time, which in turn could determine the onset of structural changes prior to irreversible damage. The RH impact is measured as surface deformation from interference fringes, using a custom-made real time holography system with interferometric precision termed digital holographic speckle-pattern interferometry (DHSPI). The main observations presented here are a hysteresis in the dynamic sorption isotherm and a greater rate of displacement during the drying. A long-term experiment was performed to identify signs of ageing of the sample. The evolution of the mass and the rate of displacement stayed similar, an offset with an interesting behavior was observed and highlights ageing of wood. In order to produce a future preventive model for distinct art objects it is necessary to determine a deformation threshold for each material. In this context the study was planned to continue with organic samples bearing variable density and thickness under longer-term RH cycles and monitoring until the samples show visible signs of irreversible damage.

Highlights

  • The impact of the environmental conditions and climate changes like the changes in relative humidity (RH) on organic art materials is worldwide studied as an essential preventive conservation measure in cultural heritage (CH) [1,2]

  • Depending on the ambient RH the material cycles of moisture adsorption and desorption is the dominant process for a material to maintain equilibrium with its environment; a process considered as most critical for physicochemical and structural alterations [4,5,6]

  • The results prove that the digital holographic speckle-pattern interferometry (DHSPI) technique is a direct surface monitoring method and can be very useful towards the decisive prevention strategies on collections and monuments

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Summary

Introduction

The impact of the environmental conditions and climate changes like the changes in relative humidity (RH) on organic art materials is worldwide studied as an essential preventive conservation measure in cultural heritage (CH) [1,2]. Especially wood, are in constant interaction with the surrounding moisture in the environment [1,2,3]. Organic materials based on carbon and hydrogen molecules are porous and characterized as hydrophilic. When the pores are of the order of thousands of a cm, as in the case of wood and cellulose, they have a large internal surface area allowing through capillary rise significant water absorption and moisture transmission. As water vapor molecules in the air are adsorbed to the internal surfaces the water content increases provoking structural expansion [7,8,9]

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