Abstract
AbstractTwo new nickel(II) complexes, [Ni(4, 4′‐bpy)(H2O)4]n·n(cpp)·0.5nH2O (1) and [Ni(cpp)(4, 4′‐bpy)(H2O)2]n (2) [4, 4′‐bpy = 4, 4′‐bipyridine, H2cpp = 3‐(4‐carboxyphenyl)propionic acid] were synthesized and characterized by single‐crystal X‐ray diffraction, elemental analysis, IR spectroscopy, and thermal analysis. In complex 1, NiII ions are bridged by 4, 4′‐bpy into 1D chains, and cpp ligands are not involved in the coordination, whereas in complex 2, cpp ligands adopt a bis(monodentate) mode and link NiII ions into 2D (4, 4) grids with the help of 4, 4′‐bpy ligands. Triple interpenetration occurs, which results in the formation of a complicated 3D network. The difference in the structures of the two complexes can be attributed to the different reaction temperatures and bases.
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