Impact of pulping routes of rice straw on cellulose nanoarchitectonics and their behavior toward Indigo dye

Abstract

This work deals with emphasizing the relation between particle dimension distribution of nanocellulose (PDD) particles with its efficiency as stabilizing/adsorbent agent of Indigo dye. In this respect, different pulping reagents were used in preparation of Rice straw pulps as precursors for nanocelluloses using acid hydrolysis and oxidizing agents [(KMnO4 and NH4)2S2O8] methods. The PDD was estimated by indirect method through processing the TEM images using the software ImageJ. The resulting nanocelluloses were also characterized by X-ray diffraction (XRD) and Fourier-transform infrared spectra (FTIR) together with sulfate ester and carboxyl contents. The data showed the effective role of pulping reagent on PDD. The cellulose nanocrystals (CNCs) from NaOH-AQ pulp, with the longest crystal length (204.4 ± 107.8 nm) and the lowest diameter (6.7 ± 2.3 nm), exhibited most stabilized suspension of dye; however, the highest adsorption capacity was accompanied the oxidized nanocellulose (Ox-NC) from neutral RS pulp with lowest PDD (4.98 ± 1.6 and 90.5 ± 3.14), together with highest COO content (476.46 μmol/g).