Impact of neodymium oxide (Nd2O3) substitution in barium–boron-phosphate glasses: A pathway to superior mechanical, optical, and radiation shielding performance

Abstract

This study delves into the impact of substituting Nd2O3 for Na2O in Barium–Boron-Phosphate glasses, aiming to enhance their mechanical strength, optical characteristics, and radiation shielding efficacy. Glasses with a composition of 50B2O3 + 20P2O5 + 20BaO + (10-x)Na2O + xNd2O3 (x = 0, 1, 2, 3, 4 mol%) were synthesized and characterized. The findings indicate that as the Nd/Na ratio increases, the density of the glass also rises within the range of 3.77–4.23 g/cm3. Moreover, the addition of Nd leads to notable alterations in the optical characteristics of the resulting glasses. Specifically, there is a shift observed in the UV absorption edges, coupled with a noticeable increase in absorption at visible wavelengths. Moreover, Nd2O3 addition reduced the Urbach energy (from 0.6018 to 0.2239 eV for Nd0-Nd4) and the optical band gap indicating improved electronic structure and decreased disorder. The mechanical properties studied using the Makishima-Mackenzie model show As the replacement ratio of Nd2O3 increases, there is a noticeable improvement in the glass's mechanical robustness. Importantly, Glasses with high Nd/Na ratio in their composition exhibit enhanced radiation shielding capabilities, evidenced by increased mass attenuation coefficients and effective removal cross-sections for photons and fast neutrons, respectively. These findings suggest that Nd2O3-doped glasses offer a promising pathway for developing superior radiation shielding materials with tailored properties for diverse applications in nuclear facilities, medical devices, and space exploration equipment.