Abstract
ABSTRACTSmectogenic chiral esters with three-ring rigid core were examined by infrared and Raman spectroscopy. These compounds differ in the type of chiral centre, length of non-chiral chain and substitution of phenyl ring by fluorine atoms. The influence of molecular structure on the type of handedness of helical structure, as well as the shift and split of absorption bands on IR and Raman spectra were determined. The change of the length of non-chiral terminal chain has the most significant influence on the type of helical twist sense. All considered structural elements of tested compounds have the biggest influence on the value of wavelength of vibrational bands related to the carbonyl group located in the rigid core.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
