Abstract
The impact of ozone mini-holes over the extra-tropics of the northern hemisphere on the heterogeneous ozone chemistry is investigated, based on simulations with the coupled climate-chemistry model ECHAM4.L39(DLR)/CHEM. Ozone mini-holes are synoptic-scale regions of strongly reduced total ozone, directly associated with upper troposphere high pressure systems. The simulated mini-hole events are validated with a mini-hole climatology based on daily ozone measurements with the total ozone mapping spectrometer (TOMS) instrument on the satellite Nimbus-7 between 1979 and 1993. Furthermore, the impact of mini-holes on the stratospheric heterogeneous ozone chemistry is investigated indirectly. For this purpose, polar stratospheric cloud formation inside mini-holes is suppressed during the model simulation. Heterogeneous processes inside mini-holes amount to one third of the heterogeneous ozone destruction in general over northern mid- and high-latitudes during winter (January–April). This ozone perturbation subsides and recovers during summer with an e-folding time of two months.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
