Impact of carbonization on oak wood δ18O: A preliminary study

Abstract

The carbonization process induces significant physical, elemental, and structural transformations of wood. In this study, the modification of δ18O in wood during the carbonization process was investigated in conjunction with elemental analysis, infrared spectroscopy (FTIR), and Rock-Eval thermal analysis, to explore the connection between the chemical composition of the materials and the alterations in δ18O. Quercus petraea wood samples were experimentally burned at temperatures ranging from 200 °C to 1000 °C under inert (pyrolysis) and oxidative atmospheres. The results reveal that the modification of δ18O values in charred wood can be described as a sequential two-step process. The initial step, occurring below 300 °C, involves the volatilization and preferential degradation of thermolabile compounds, leading to an increase of +1.6‰ in δ18O. The subsequent step, below 700 °C, results in a decrease in δ18O values of –21.6‰, primarily driven by the thermal degradation of cellulose and lignin, as well as the increase of aromaticity and reorganization. The components and the δ18O of wood undergo distinct changes in combustion mode, due to different carbonization kinetics as evidenced by FTIR and elemental analysis. To assess the intensity of the carbonization process, influenced by temperature, oxygen availability, and wood characteristics, the H/C atomic ratio, a good indicator of aromaticity, is used. A non-linear regression model was established, relating δ18O to the H/C atomic ratio, thereby demonstrating that δ18O values undergo changes as wood aromatization progresses, independent of the carbonization conditions. The second order model has a mean confidence interval of 1.9‰ and a prediction interval of 8.1‰. This work provides a fundamental understanding of the connection between the chemical composition of woody materials, alterations in δ18O, and the carbonization process, offering valuable insights for further studies and applications related to oxygen-related information that may be preserved in charcoals.