Abstract

This study examines the impact of the addition of bio-ethanol/bio-ETBE on the main volatility properties of gasoline. Although several studies have been published on the addition of ethanol or ETBE to gasoline, the simultaneous addition of these oxygenates has not been studied by taking the maximum oxygen content of 3.7% m/m into account. The EN 228:2012-A1:2017 standard specifies the requirements for marketed unleaded gasoline. This standard is able to determine, among other things, a gasoline type with a maximum oxygen content of 3.7% m/m and sets the maximum limits for ethanol content at 10% v/v and 22% v/v for ethers with a minimum five carbon atoms, such as ΕΤΒΕ. Five refinery fractions were mixed in various proportions and were used as base fuels. A total of 30 samples were prepared by blending the base fuels with bio-ethanol/bio-ETBE. In each of these base fuels, bio-ethanol was added in concentrations up to 10% v/v. Subsequently, bio-ETBE was added to each of these fuels in concentrations up to 20.8% v/v for use as a stabilizer. All of the samples were examined using the EN ISO 13016-1 and EN ISO 3405 test methods while considering the volatility requirements set by EN 228. The results showed that the addition of bio-ETBE has a beneficial effect on the volatility characteristics of the samples, as it reduces the vapor pressure of the final blend and sets all fuels in compliance with the required specification limits set by the EN 228 standard.

Highlights

  • The specification according to European standard European Standards (EN) 228 sets limits on vapor presThe specification according to European standard EN 228 sets limits on vapor pressure sure (DVPE, equivalent to Reid method)

  • Thisand figure shows the ship between the vapor pressure and the bio-ethyl tert-butyl ether (ETBE)

  • ContentFigure in the samples the correspondrelationship between the vapor pressure and the bio-ETBE content in the samples and the ing amount of bio-ethanol needed to be at a level where the maximum oxygen content limit corresponding amount of bio-ethanol needed to be at a level where the maximum oxygen of 3.7% m/m is not exceeded

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. The last few decades have been defined by immense concerns regarding environmental pollution and climate change. Sustainable development has become a global goal, especially in Europe, where the fight against climate change has become a political priority. As a means to this aim, the use of automotive fuels derived from biomass and severe strict fuel specifications have been introduced through stringent demanding environmental regulations [1,2]

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