Impact of annealing on the characteristics of 3D-printed graphene-reinforced PLA composite

Abstract

Manufacturing through additive techniques, especially utilizing the fused filament fabrication (FFF) method, is a transformative technology revolutionizing design and manufacturing. FFF builds parts layer by layer using thermoplastic polymer and polymer composite filaments. However, weak interlayer connections often lead to low interlaminar resistance in printed structures. Recent studies suggest that post-deposition heat treatments can mitigate this issue by reducing internal thermal stresses and enhancing layer adhesion, thereby improving part properties. This research delves into the impact of annealing heat treatment on a composite of Polylactic Acid (PLA) reinforced with graphene. The annealing process was conducted at temperatures of 90, 100, and 120 °C for durations of 60, 120, and 240 min. The annealing response of the graphene-reinforced PLA composite is compared to that of natural PLA for reference, analyzing its effects on electrical, thermal, chemical, and mechanical properties. Chemical characterization was performed using X-ray diffraction (XRD), Raman spectroscopy, and Fourier-transform infrared spectroscopy (FTIR). Thermal properties were analyzed via thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Electrical properties were assessed by measuring resistance, resistivity, and conductivity. Mechanical properties were evaluated through tensile, flexural, notch sensitivity, impact tests, and hardness measurements. The results demonstrated that annealing of graphene-reinforced PLA and natural PLA did not alter their functional groups but increased their crystallinity. This treatment improved thermal stability, electrical conductivity, and mechanical properties, including tensile strength, flexural strength, and Shore D hardness. However, it reduced impact and notch sensitivity resistances. The increased crystallinity had a greater beneficial impact on some properties than the graphene reinforcement. These findings have potential applications in the automotive, aerospace, electronics, and medical sectors, given the increasing use of PLA in these industries.