Impact of a novel phosphorus-nitrogen flame retardant curing agent on the properties of epoxy resin

Abstract

A phosphorus-nitrogen flame retardant curing agent diethyl phosphonic p-Phenylenediamine diamide (DEPPPD) was synthesized. The chemical structure of the obtained compound was identified by Fourier transform infrared (FTIR), 1H nuclear magnetic resonance (1HNMR), and mass spectroscopies. A series of t hermosetting systems were prepared by conventional epoxy resins (E-44) and DEPPPD. The effects of DEPPPD on flame retardancy, thermal degradation behavior, mechanical properties and the morphologies of char residues of EP/DEPPPD thermosets were investigated. The results demonstrated that when the phosphorus content of 2.88 wt%, EP-3 successfully passed UL-94 V-0 flammability rating, the LOI value was as high as 31.1%, the impact strength and tensile strength of it was 6.50 KJ m−2 and 48.21 MPa, the adhesive strength could reach 14.61 MPa, respectively. The TGA results indicated that the introduction of DEPPPD promoted EP matrix decomposed at a lower temperature, the rate of the thermal decomposition also decreased compared with EP-0. The residual char ratio of 800 °C was increased whether in nitrogen or in the air. The morphological structures of char residue were more compact and homogeneous which could prevent the heat transmission and diffusion, limit the production of combustible gases and reduced the heat release rate.