Immobilized palladium nanoparticles on MNPs@A‐N‐AEB as an efficient catalyst for C‐O bond formation in water as a green Solvent

Abstract

Palladium nanoparticles immobilized on the magnetic nanoparticles@2‐amino‐N‐(2‐aminoethyl) benzamide (MNPs@A‐N‐AEB.Pd0) have been presented as an efficient, and reusable magnetically heterogeneous catalyst for the C‐O coupling reaction, namely Ullmann condensation reactions in an aqueous medium. This heterogeneous catalyst shows superior reactivity for the C‐O arylation of different aryl halide (chloride, bromide, and iodide) with phenol derivatives to afford the desired products in good to excellent yields within short reaction time. Moreover, the catalyst can be easily recovered and reused for seven runs without loss of catalytic activity. The catalyst was characterized by several techniques, such as FT‐IR, SEM, TEM, EDS, XRD, TGA and ICP‐OES.