Abstract
The reaction of catalytic hydroxylation of olefins by organic hydroperoxides in the presence of osmium carbonyl clusters supported on polymer matrices is studied. The process occurs with the predominant formation of unsaturated alcohols. The oxidative coupling of olefins with the formation of nonconjugated dienes and in which the double bonds remain intact occurs in parallel. In the course of the reaction, changes in the chemical structures of the initial osmium clusters are not observed.
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