Abstract
Due to their large surface areas, tunable functionality, and diversiform building blocks, metal–organic frameworks (MOFs) have arisen great attention in the last few decades. Nevertheless, most of MOFs show poor water stability, which seriously hinders their further applications. In this study, through the immobilization of polyoxometalate in a water unstable cage-based MOF material {[(Cu4Cl)(CPT)4(H2O)4]·3NO3·5NMP·3.5H2O} (1), in which HCPT = 4-(4-carboxyphenyl)-1,2,4-triazole and NMP = N-methyl pyrrolidone), via a simple one-pot solvothermal reaction, a new hybrid material {[(Cu4Cl)(CPT)4]·(HSiW12O40)·31H2O} (2) can be fabricated. The hybrid material 2 shows a nearly identical network structure to that of 1 but possesses much higher water and chemical stability. Moreover, the visible light dye degradation performance for 2 in water has been illustrated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
