Immobilization of hydrochar in cellulose beads for eradicating paracetamol from synthetic and sewage water

Abstract

Sodium carboxymethyl cellulose polymer was used as a support matrix in immobilizing activated hydrochar derived from bamboo using hydrothermal carbonization. The structural and textural morphology of the beads were studied using FTIR, XRD, SEM/EDS, BET and TGA. Activated hydrochar showed a rough surface with irregular spherical shaped structure. Various oxygenated functional groups in composite beads and activated hydrochar were identified that assist in interaction with PARA pollutant. TGA analysis showed weight loss at three stages 200 °C, 365 °C and 710 °C that leads to complete disintegration of composite beads. BET analysis showed a variation in the surface area between activated hydrochar and beads which could be due to air drying process. Batch adsorption test was conducted for investigating the efficiency of beads in removing PARA from water. Pseudo-second order and Langmuir isotherm fitted the best highlighting chemical mode of adsorption with homogenous interaction on the adsorbent surface. 48.12 mg g−1 was the maximum adsorption capacity estimated from sorption between beads and PARA. For practical applications beads were effectively used in reducing COD levels of PARA spiked sewage water with the defined experimental parameters. Ethanol would be effectively used as regenerating solvent in recycling the beads for the betterment of cost reduction. The activated hydrochar immobilized cellulose beads would be successfully applied as adsorbent in removing target pollutants from water thereby reducing the hurdles faced with respect to fine particles in water treatment.