Iminium-Bridged Resorcinol-Silane Networks and Their Pyrolyzed Derivatives as Electrode Materials for the Electrocatalytic Oxygen Reduction Reaction and Supercapacitors.

Abstract

We report the synthesis of iminium-bridged resorcinol-silane (I-R-S) gel networks through the reaction of resorcinol with 3-aminopropyl triethoxysilane (APTES) in the presence of acetone under ambient conditions. Ambient pressure drying leads to monolithic gels with minimal shrinkage and cracks, eliminating the use of conventional supercritical drying. The gels were found to have bulk and skeletal densities of 0.90 and 1.23 g/cm3, respectively. Interestingly, it was found that acetone plays the dual role of solvent (solubilizing the precursors, APTES, and resorcinol) and reactant by reacting with amine present in APTES to form imine functionalities. Furthermore, the imine was found to react with resorcinol to form I-R-S gel networks. The I-R-S gel was found to be hydrophobic with a contact angle of between 99 and 103°. Upon pyrolysis at higher temperatures (600, 800, and 1000 °C), the I-R-S gels transformed to silica containing N-doped carbon as confirmed by X-ray photoelectron spectroscopy (XPS). Further removal of silica by hydrofluoric acid (HF) treatment lead to porous N-doped carbon which was found to effectively electrocatalyze the oxygen reduction reaction (ORR) by mixed 3e- pathway. Note that the sample pyrolyzed at 600 °C followed by treatment with HF displayed an ∼2e- pathway with a higher peroxide yield of 91%. Due to the high specific surface area and increased microporosity, the pyrolyzed samples treated with HF were found to exhibit a specific capacitance of 213 F/g with capacity retention of 90% for up to 2100 cycles.