Abstract
Reaction of the dimolybdenum tetraimido complex [(MeC 5H 4)Mo(NPh)(μ-NPh)] 2 with an excess of para-tolyl isocyanate results in the stepwise exchange of terminal imido ligands to yield [(MeC 5H 4) 2Mo 2(N- p-tolyl)(NPh)(μ-NPh) 2] and [(MeC 5H 4)Mo(N- p-tolyl)(μ-NPh)] 2. Prolonged heating does not, however, result in substitution of the bridging phenylimido ligands.
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