Abstract
We demonstrate a technique for facile encapsulation and adhesion of micro- and nano objects on arbitrary substrates, stencils, and micro structured surfaces by ultrathin graphene oxide membranes via a simple drop casting of graphene oxide solution. A self-assembled encapsulating membrane forms during the drying process at the liquid-air and liquid-solid interfaces and consists of a water-permeable quasi-2D network of overlapping graphene oxide flakes. Upon drying and interlocking between the flakes, the encapsulating coating around the object becomes mechanically robust, chemically protective, and yet highly transparent to electrons and photons in a wide energy range, enabling microscopic and spectroscopic access to encapsulated objects. The characteristic encapsulation scenarios were demonstrated on a set of representative inorganic and organic micro and nano-objects and microstructured surfaces. Different coating regimes can be achieved by controlling the pH of the supporting solution, and the hydrophobicity and morphology of interfaces. Several specific phenomena such as compression of encased objects by contracting membranes as well as hierarchical encapsulations were observed. Finally, electron as well as optical microscopy and analysis of encapsulated objects along with the membrane effect on the image contrast formation, and signal attenuation are discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.