Image analysis for interfacial area and cocontinuity detection in polymer blends

Abstract

A novel image processing method was developed to extract interfacial area concentration measurements from 2D micrographs of immiscible polymer blends. Although this method can be used for analyzing different types of 2D micrographs such as optical or transmission electron microscopy images, it was designed for analyzing scanning electron microscopy (SEM) images. The method operates by detecting edges within the images and using standard image processing operations to selectively eliminate false edges. SEM images of polyethylene oxide/polystyrene (PEO/PS) blends were analyzed using this image processing method to measure the amount of interfacial area in the samples. Interfacial area per unit volume exhibits maxima for blend compositions at the boundary between droplet and cocontinuous morphologies. In addition to the detection of cocontinuity, the interfacial area measurements facilitated by this method may be used in future investigations of blend dynamics, including coalescence, drop deformation, and blend rheology studies. These measurements may also be used to quantify the effects of compatibilizers on blend morphology.