Ignition and combustion of synthetic nickel mattes in simulated flash smelting conditions

Abstract

The ignition and oxidation behavior of synthesized sulfur-lean nickel mattes was investigated using a laminar flow furnace simulating the conditions in the flash smelting reaction shaft to explore the ignition and oxidation processes of sulfur-lean electric furnace mattes obtained from slag cleaning. The experiments were conducted at 800–1100 °C with 40–85 vol% O2 in the reaction gas. Scanning electron microscopy equipped with energy-dispersive X-ray spectrometry was used to analyze the surface morphology and mineralogical compositions of the samples. Chemical analysis was employed to determine the sulfur remaining in the samples. The ignition temperature of the sulfur-lean nickel mattes was found to be below 800 °C. The highest sulfur removal from mattes was achieved under the most oxidizing conditions. The oxidation of the metallized nickel mattes started with preferential oxidation of iron and sulfur, forming sulfur dioxide and a porous iron oxide-rich rim. Particles were observed to melt completely and even to fragment due to fast combustion reactions and the formation of sulfur dioxide inside. The present results provide valuable insights into the mechanism of sulfur-lean nickel matte smelting in flash smelting furnaces.