Abstract

Iron and steel production contributes to ~10% of global CO2 emissions. In recent decades, different scenarios and low-emission pathways have been taken up by steelmaking industries with the collaboration of universities and research institutes to tackle this problem. One of the most promising novel methods to replace the current steelmaking process is the low-temperature electrolysis of iron oxide. This technology is currently being developed under the H2020 ΣIDERWIN project, a European project led by ArcelorMittal, the world’s leading steel and mining company. The ΣIDERWIN project aims at developing an innovative electrochemical process to transform iron oxide into steel metal plates. This process produces steel by electrolysis without direct CO2 emissions. In this operation, electrical energy and iron oxide are converted into chemical energy consisting of separated iron metal from the oxygen gas. It is a disruptive innovation that entirely shifts the way steel is presently produced. One of the advantages of this process is the fact that, in addition to iron oxide (hematite), it is possible to feed this process with other iron-containing raw materials. An alternative raw material which is being studied to be used in this process is bauxite residue (BR), the waste material from the Bayer process for alumina production. The iron oxide of the conversion of bauxite residue to metallic iron is under investigation, and insights are showing that it could follow up the electrochemical route for sustainable iron production. This research deals with the effect of the current density and temperature on current efficiency comparing two different raw materials, pure iron oxide–hematite and bauxite residue.

Highlights

  • Climate change forces the world of metallurgy to take big steps towards sustainability

  • The present paper is focused on the third mentioned technique, an electrolysis-based process that started developing during the ULCOWIN (Ultra Low Carbon Dioxide in Steelmaking) program supported by the European Commission and the steel industry in Europe at the beginning of the 2000s [2,3]

  • A lot of studies have been carried out and shown that this process is valuable for the future of iron production, and pilot plant construction is ongoing in terms of the ΣIDERWIN process, the evolution of the aforementioned ULCOWIN technology

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Summary

Introduction

Climate change forces the world of metallurgy to take big steps towards sustainability. The present paper is focused on the third mentioned technique, an electrolysis-based process that started developing during the ULCOWIN (Ultra Low Carbon Dioxide in Steelmaking) program supported by the European Commission and the steel industry in Europe at the beginning of the 2000s [2,3]. This technology consists of low-temperature electrolysis that produces metallic iron from iron oxide, basically hematite. The quantity of metallic iron produced is lower, and there are indications that the mechanism may differ

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