Abstract

The identification of hazardous chemicals based on hyperspectral imaging is an important emergent means for the prevention of explosion accidents and the early warning of secondary hazards. In this study, we used a combination of spectral curve matching based on full-waveform characteristics and spectral matching based on spectral characteristics to identify the hazardous chemicals, and proposed a method to quantitatively characterize the matching degree of the spectral curves of hazardous chemicals. The results showed that the four hazardous chemicals, sulfur, red phosphorus, potassium permanganate, and corn starch had bright colors, distinct spectral curve characteristics, and obvious changes in reflectivity, which were easy to identify. Moreover, the matching degree of their spectral curves was positively correlated with their reflectivity. However, the spectral characteristics of carbon powder, strontium nitrate, wheat starch, and magnesium–aluminum alloy powder were not obvious, with no obvious characteristic peaks or trends of change in reflectivity. Except for the reflectivity and the matching degree of the carbon powder being maintained at a low level, the reflectivity of the remaining three samples was relatively close, so that it was difficult to identify with the spectral curves alone, and color information should be considered for further identification.

Highlights

  • We investigated 8 hazardous chemicals, red phosphorus, corn starch, carbon powder, strontium nitrate, wheat starch, sulfur, potassium permanganate, and magnesium

  • In terms of the relationship between matching degree and reflectivity, it can be known by calculation that for the four hazardous chemicals with obvious spectral characteristics, sulfur, red phosphorus, potassium permanganate, and corn starch, the matching degree of their spectral curves was positively correlated with their reflectivity

  • The long-distance and non-contact detection and identification of hazardous chemicals based on hyperspectral imaging are important emergent means for the prevention of explosion accidents and the early warning of secondary hazards

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. Severe explosion accidents have occurred frequently, including the “8.2” explosion accident in Jiangsu Zhongrong in 2014, the “8.12” fire and explosion accident at Tianjin Port in 2015, and the “8.4” explosion accident at Beirut Port in 2020. The environment of an explosion accident site is complex, often with numerous explosives and pollutants distributed over the site. At the scene of an accident, it is important to quickly locate the core area of the explosion as well as the type and distribution of explosives and pollutants, to provide disaster scene awareness, early warning of secondary hazards and support for decision-making in post-accident rescue. There is an urgent need to expand the study of in situ identification and detection of typical inflammable and explosive hazardous chemicals at explosion accident scenes

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