Abstract

The identification of time-varying parameters (e.g., directly inaccessible in situ signals in vacuum and low-temperature environments) is prevalent for characterizing the dynamics of quantum processes. Under certain circumstances, they can be identified from time-resolved measurements via Ramsey interferometry experiments, but only with specially designed probe systems can the parameters be explicitly read out, and a rigorous identifiability analysis is lacking, i.e., whether the measurement data are sufficient for unambiguous identification. In this paper we formulate this problem as the invertibility of the input-output mapping associated with the quantum system for which an algebraic identifiability criterion is derived based on the system's relative degree. The invertibility analysis also leads to an inversion-based algorithm for numerically identifying the parameters, which is computationally much more efficient than nonlinear regression methods. The effectiveness of the criterion are demonstrated by numerical examples.

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