Identification of the sources and influencing factors of the spatial variation of heavy metals in surface sediments along the northern Jiangsu coast

Abstract

Determining the sources and factors influencing the spatial variation of heavy metals in the surface sediments of tidal flats is important for controlling and reducing heavy metal pollution. We used principal component analysis and partial least square regression to analyse the distribution characteristics, sources, and factors influencing the spatial variation of nine heavy metals (As, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn) in the surface sediments of tidal flats along four sites located on the northern Jiangsu coast. Our results indicate that the northern three sampling areas had a high heavy metal content, whereas the southern sampling area had a low heavy metal content. The heavy metals Mn and Pb are related to both natural and anthropogenic sources, whereas V and Cr are primarily derivatives of human activities, and As, Co, Cu, Ni, and Zn are primarily a result of natural processes. The spatial variation of Mn and Pb was primarily affected by the total inorganic carbon and clay content (positive affect) as well as the sand and silt content (negative affect). The spatial variation of V and Cr was primarily related to silt, clay, and total phosphorus content (positive influence) as well as sand (negative influence). In addition, the spatial variation of As, Co, Cu, Ni, and Zn was primarily influenced by the total organic carbon and clay content (positive effect) as well as sand and pH (negative effect). The grain size of sediments plays an important role in the spatial variation of heavy metals in the surface sediments of tidal flats, with fine-grained clay materials being related to the enrichment of heavy metals. The results of our study are important for the control and reduction of heavy metal pollution in coastal sediments, protecting both the ecological environment and human health.