Identification of nitrate sources and transformations in basin using dual isotopes and hydrochemistry combined with a Bayesian mixing model: Application in a typical mining city

Abstract

The external nitrogen load input caused by human activities exacerbates the eutrophication process of aquatic ecosystems in mining areas, causing water quality problems. However, knowledge of the sources and environmental behavior of nitrate in the surface water of mining areas is still very limited. This study investigated the nitrate content and spatiotemporal variation characteristics of surface water in the Linhuan mining area, identified the sources and transformation processes of nitrate using isotopes and hydrochemistry, and evaluated the contribution rates of different potential nitrate sources based on a Bayesian mixing model. The nitrogen pollution in the surface water in the mining area seriously exceeded class Ⅴ of the Environmental Quality Standard of Surface Water of China (GB3838-2002). The NO3− content ranged from 0.87 to 3.41 mg/L, showing obvious seasonal and spatial differences. Isotope and NO3−/Cl− analysis indicated that nitrate in the subsidence area water (SAW) was mainly derived from chemical fertilizer (NF) and soil organic nitrogen (NS), while nitrate in the mainstream of the Huihe River water (HRW) was mainly derived from manure/sewage (MS). The nitrate in the tributary of the Baohe River water (BRW) was mainly derived from soil NS, and nitrification was a nitrogen conversion pathway in the soil. The results of the Bayesian mixing model showed that the main sources of nitrate in the BRW, HRW and SAW were NF (34.5%), MS (68.8%) and NF (40.8%) in the wet season, and NS (33.4%), MS (70.9%) and NF (58.1%) in the dry season, respectively. The results of this study provide a new integrated method for the identification of nitrate pollution sources in mining areas, and this method can be used to improve the biogeochemical information of nitrogen in the aquatic ecosystems of mining areas and help formulate relevant measures to reduce water nitrogen pollution.