Abstract
1H solid-state nuclear magnetic resonance (NMR) spectroscopy was used to study intrinsic hydrogen (H) impurities in zinc oxide (ZnO), which play a key role in its n-type conductivity. Two 1H signals were resolved, and assigned for the first time, to interstitial H species (Hi) and H species substituting for oxygen ions (HO), with the help from the model compound zinc hydroxide (ɛ-Zn(OH)2) and 1H→17O double resonance NMR spectroscopy.
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