Abstract
A new method for the identification of electrode surface blocking, based on the measured differences of the diffusion limiting current densities in a thin-layer cell and in a cell with rotating-disk electrode is presented. An equation describing the diffusion limiting current density dependence on the inter-electrode distance in a thin-layer cell was derived. Experimental results were obtained from measurements with model electrodes to demonstrate the possibilities for unambiguous identification of surface blocking phenomena. A model electrode, covered with a partially conductive blocking layer was also discussed and the appearance of two diffusion limiting current density levels on the voltammograms was experimentally verified.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.