Abstract
AbstractThe development of catalyst‐controlled site‐selective C(sp3)−H functionalization is a current major challenge in organic synthesis. This paper describes DFT‐guided identification of pentavalent silicate species as a novel bond‐weakening catalyst for the α‐C−H bonds of alcohols together with a photoredox catalyst and a hydrogen atom transfer catalyst. Specifically, Martin's spirosilane accelerated α‐C−H alkylation of alcohols.magnified image
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