Abstract
An ideal n=3 member of Ruddlesden–Popper (RP) phase Ca4Mn3O10 was obtained by solid-state reaction under high pressure. This phase has been studied by transmission electron microscopy, convergent beam electron microscopy, high-resolution transmission electron microscopy, and electron energy loss spectroscopy. The lattice parameters are derived as a=b=0.37 nm and c=2.69 nm with a space group of I4/mmm, which is the space group of ideal RP phase. The advantages of high pressure sintering are discussed.
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