Abstract

Not classified as free radicals are atoms or molecules in ground or excited electronic states with multiplicities larger than two (e.g. O, P; O2, Σ; N, S; molecules in excited triplet states), transition metal ions and their complexes deriving their paramagnetism exclusively or mainly from dand felectrons and charge transfer complexes. However, a number of polyatomic molecular species which do not fulfill the above definition are included because their properties closely resemble those of structurally closely related free radicals. These are

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