Abstract
New four-coordinated tetrahedral Cu(I) complexes of the general formula [CuCl(HL)(PPh3)2] have been synthesized from the reactions between [CuCl2(PPh3)2] and N-(dibenzylcarbamothioyl)benzamide (HL1) or N-(methylpentylcarbamothioyl)benzamide (HL2) in benzene. The complexes have been characterized by elemental analyses, IR, UV–Vis, 1H, 13C and 31P NMR spectroscopy. The molecular structures of [CuCl(HL1)(PPh3)2] (1) and [CuCl(HL2)(PPh3)2] (2) were determined by single crystal X-ray crystallography. Each complex displays a distorted tetrahedral, ClP2S, coordination geometry with hypodentate coordination of acylthiourea ligands which coordinate the Cu(I) centre through sulfur atom exclusively.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
