Abstract
Abstract The first hypervalent compounds containing both a pentacoordinated silicon atom and a pentacoordinated phosphorus atom were synthesized by the cooperative three-component reaction of a phosphoranide, a silane, and THF accompanying the ring opening of THF, or by the nucleophilic addition of phosphoranylalkoxides to a silane. Hydrolysis of the phosphoranyloxysilicate and phosphoranylalkoxysilicates gave the hydroxysilicate and the corresponding phosphoranes.
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