Abstract
Recent developments in chemistry of hypervalent organoantimony and -bismuth complexes with bidentate (C,E)- and tridentate (E,C,E)- and (C,E,C)-ligands are reviewed. The ligands are bonded to the antimony or bismuth atoms through carbon atoms and through intramolecular coordination with dative bonds from nitrogen, oxygen or sulfur atoms. Syntheses, structures including chirality aspects, reactions, fluxional behavior, biological aspects and applications in the field of catalysis and organic syntheses are considered in this review.
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