Abstract

Hyperspherical coordinates are used to study electron correlations in the radial motion of a four-electron atom within the model of s{sup 4} configurations. We identify groups of hyperspherical adiabatic potential curves that support singly, doubly, triply, and quadruply excited states. By examining the nodal structures of the channel functions, we show that it is possible to relate the number of nodal surfaces in the hyperangles and the principal quantum numbers used in the independent particle picture.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.