Abstract

The TaI line 6356.14 A, up to now classified as the transition 5d36s2a4P5/2−5d36s(a5F)6p z4F72/0, is a blend with a second transition, which is related to the additional levels 5d4(b3G)6s a4G9/2−39641.24 cm−1J=7/2°. Using laser excitation with optogalvanic and laser-induced fluorescence detection, the hyperfine constants of the four levels involved and the distance of the center wavelengths of the two fine structure transitions could be determined.

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