Abstract
The J = 1−0 transitions of the microwave spectra of H28Si35Cl, H28Si37Cl, H29Si35Cl, and H30Si35Cl were measured at 14−15 GHz. The effective rotational constants are obtained, and the chlorine nuclear quadrupole coupling constants and nuclear spin-rotation constants of the four isotopomers are determined for the first time. These constants are compared with their values obtained from ab initio calculations.
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