Abstract
AbstractThe results of the kinetic study of melt and solution polymerization at the 1,3‐dipolar cycloaddition reaction of the AB2 monomer – 2‐azido‐4,6‐bis(prop‐2‐yn‐1‐yloxy)‐[1,3,5]‐triazine (ABPOT) are presented in this work as well as the results of the 13C‐NMR characterization of the obtained hyperbranched poly([1,2,3]‐triazole‐[1,3,5]‐triazine)s. It is established, that the first‐shell substitution effect during polyaddition process and unusual high degree of branching (up to 0.9) of polymers synthesized in melt are held.
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