HYGROSCOPIC WATER CONTENT AS AN INDICATOR OF SOIL DISPERSITY:THERMODYNAMIC BASIS AND EXPERIMENTAL VERIFICATION

Abstract

The adsorption properties of dispersed systems are determined by their surface energy, therefore the indicators of hygroscopy (adsorbed water content) and dispersity (specific surface area of the solid phase) of soils and sediments are in close mutual correlation. This well-known empirical fact received a new fundamental interpretation based on the theory of disjoining water pressure according to Deryagin in the form of a thermodynamic equation connecting the specific surface area, hygroscopic water content of soil samples and the relative humidity of the air in the laboratory room. The theoretical equation allowed us to substantiate the methodology for quantifying the hydrophilic specific surface area of soil samples based on widespread data on their hygroscopy. A comparison of the new method with the standard BET-analysis of the specific surface area, as well as with the previously proposed physically based method for its determining by the slope of thermodynamic water retention curves, showed their statistically reliable agreement in a wide range of estimated specific surface area values from 5 to 340 m2×g-1 for soil samples of different genesis and texture.