Abstract

The reaction of congeners of polychlorinated biphenyls with potassium hydroxide has been studied using different polyalkanolamines as the solvent. Predominant formation of hydroxy derivatives under the conditions of thermodynamic control has been observed. The conversion of the congeners of polychlorinated biphenyls in the hydroxylation reaction and the number of the introduced hydroxy groups depends on the basicity of the polyalkanolamine.

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