Abstract

Hemin chloride is solubilised in aqueous media by non-ionic detergents of the polyethylene oxide alkylamine type to give solutions which at neutral pH contain a dinuclear esr non-detectable form within the micelles of the detergent. Addition of β-mercaptoethanol effects the formation of iron(II) protoporphyrin IX and the resulting surfactant solution of this chelate brings about the hydroxylation of aniline and provides a model system for the function of cytochrome P-450.

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