Abstract
The hydroxylation of a-Al2O3(000l) and MgO surfaces is studied in ultra-high vacuum by high-resolution electron energy loss spectroscopy (adsorbate and phonon losses being distinguished via resonance scattering) and X-ray photoemission spectroscopy. Hydroxyl groups which arise from the dissociative adsorption of H2O on a-Al2O3(0001) surfaces and low-coordinated MgO surface sites are characterized by chemical shifts and stretching frequencies.
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