Hydrous Cerium Dioxide-Based Materials as Solid-Contact Layers in Potassium-Selective Electrodes.

Abstract

This paper introduces hydrous cerium dioxide applied for the first time as a solid-contact layer in ion-selective electrodes. Cerium dioxide belongs to the group of metal oxides that exhibit both redox activity and a large surface area and therefore was considered to be an appropriate material for the solid-contact layer in potentiometric sensors. The material was examined both standalone and as a component of composite materials (with the addition of carbon nanomaterial or conducting polymer). Three cerium dioxide-based materials were tested as solid-contact layers in potentiometric sensors in the context of their microstructure, wettability, and electrical properties. The addition of hydrous cerium dioxide was shown to enhance the properties of carbon nanotubes and poly(3-octylthiophene-2,5-diyl) by increasing the value of electrical capacitance (798 μF and 112 μF for hCeO2-NTs and hCeO2-POT material, respectively) and the value of contact angle (100° and 120° for hCeO2-NTs and hCeO2-POT material, respectively). The proposed sensor preparation method is easy, without the need to use an advanced apparatus or specific conditions, and fast; sensors can be prepared within an hour. Designed hCeO2-based electrodes exhibit competitive linear range and potential stability within the wide range of pH values (2.0–11.5). Designed electrodes are dedicated to potassium determination in environmental and clinical samples.