Abstract
The single-phase CoMoO4 was prepared via a facile hydrothermal method coupled with calcination treatment at 400 °C. The structures, morphologies, and electrochemical properties of samples with different hydrothermal reaction times were investigated. The microsphere structure, which consisted of nanoflakes, was observed in samples. The specific capacitances at 1 A g−1 are 151, 182, 243, 384, and 186 F g−1 for samples with the hydrothermal times of 1, 4, 8, 12, and 24 h, respectively. In addition, the sample with the hydrothermal time of 12 h shows a good rate capability, and there is 45% retention of initial capacitance when the current density increases from 1 to 8 A g−1. The high retain capacitances of samples show the fine long-cycle stability after 1000 charge-discharge cycles at current density of 8 A g−1. The results indicate that CoMoO4 samples could be a choice of excellent electrode materials for supercapacitor.
Highlights
It is important to develop the conversion and storage of renewable alternative energy because of the rapid decay of fossil fuels
According to the mechanism of charge storage, supercapacitors could be classified into electrochemical double-layer capacitors (EDLCs) and redox electrochemical capacitors (i.e. pseudocapacitance (PCs))
In summary, the CoMoO4 microspheres have been successfully synthesized by hydrothermal growth process coupled with calcinations treatment
Summary
It is important to develop the conversion and storage of renewable alternative energy because of the rapid decay of fossil fuels. According to GCD test results, the samples show specific capacitances of 151, 182, 243, 384, and 186 F g−1 at current density of 1 A g−1 in 2 M KOH electrolyte.
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