Abstract
Three new coordination compounds, [Zn2(bppc)2(bdc)(H2O)2]·4H2O(1) [Zn4(bppc)2(o-bdc)2(ox)(H2O)2]n·2nH2O (2), [Zn2(bppc)(ox)1.5(H2O)2]n·3.5nH2O (3) (Hbppc = 2,6-bis(pyrazin-2-yl)pyridine-4-carboxylate, H2bdc = 1,4-benzenedicarboxylic acid, H2(o-bdc) = 1,2-benzenedicarboxylic acid, H2ox = oxalic acid), with different structural dimensionality (0D, 1D and 2D, respectively) have been hydrothermally synthesized and structurally characterized. Single crystal X-ray analysis revealed that compound 1 shows a dimer structure, compound 2 and 3 show one-dimensional ring chain structure and two-dimensional structure respectively. The structure differences of 1–3 show that the aromatic acid as auxiliary ligand have important influence on the final structures. Additionally, the luminescent properties of 1–3 have been investigated with fluorescent spectra in the solid state, and 1–3 display a strong fluorescent emission at room temperature and have potential applications as fluorescent-emitting materials.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
